Phase-reversal emulsion catalysis with CNT-TiO2 nanohybrids for the selective oxidation of benzyl alcohol

Chemistry. 2013 Nov 25;19(48):16192-5. doi: 10.1002/chem.201300949. Epub 2013 Nov 7.

Abstract

Mix it up: Carbon nanotube (CNT)-TiO2 nanohybrids with the potential to control the phase of an emulsion were successfully developed with a simple yet efficient method. When ruthenium was deposited on these CNT-TiO2 nanohybrid supports, they demonstrated catalytic potential for the selective oxidation of benzyl alcohol to benzaldehyde. The relationship between the emulsion properties and the catalytic mechanism is also discussed.

Keywords: carbon nanotube; catalysis; emulsion; oxidation; phase reversal.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Benzaldehydes / chemistry*
  • Benzyl Alcohol / chemistry*
  • Catalysis
  • Emulsions
  • Nanotubes, Carbon / chemistry*
  • Oxidation-Reduction
  • Ruthenium / chemistry

Substances

  • Benzaldehydes
  • Emulsions
  • Nanotubes, Carbon
  • Ruthenium
  • Benzyl Alcohol
  • benzaldehyde