Salt-responsive self-assembly of luminescent hydrogel with intrinsic gelation-enhanced emission

ACS Appl Mater Interfaces. 2014 Jan 22;6(2):757-62. doi: 10.1021/am4049354. Epub 2013 Dec 31.

Abstract

Tetraphenylethylene (TPE), an archetypal luminogen with aggregation-induced emission (AIE), was grafted to a salt-responsive peptide to yield a yet luminescent hydrogelator. After testing different parameters, we found that only in the presence of salt rather than temperature, pH, and solvent, did the monodisperse hydrogelators self-assemble into a hydrogel network with bright emission turned on. The induced luminescence was a dynamic change and enabled real time monitoring of hydrogel formation. Grating AIE molecules to stimuli-responsive peptides is a promising approach for the development of self-revealing soft materials for biological applications.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Ethylenes / chemistry*
  • Hydrogel, Polyethylene Glycol Dimethacrylate / chemistry*
  • Luminescence
  • Peptides / chemistry*
  • Sodium Chloride / chemistry

Substances

  • Ethylenes
  • Peptides
  • Hydrogel, Polyethylene Glycol Dimethacrylate
  • Sodium Chloride
  • ethylene