Smart detection of toxic metal ions, Pb2+ and Cd2+, using a 129Xe NMR-based sensor

Anal Chem. 2014 Feb 4;86(3):1783-8. doi: 10.1021/ac403669p. Epub 2014 Jan 24.

Abstract

An approach for sensitive magnetic resonance detection of metal cations is proposed. Combining the use of hyperpolarized (129)Xe NMR and of a cage-molecule functionalized by a ligand able to chelate different cations, we show that simultaneous detection of lead, zinc, and cadmium ions at nanomolar concentration is possible in short time, thanks to fast MRI sequences based on the HyperCEST scheme.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cadmium / analysis*
  • Cadmium / chemistry
  • Chemistry Techniques, Analytical / instrumentation*
  • Environmental Pollutants / analysis*
  • Environmental Pollutants / chemistry
  • Lead / analysis*
  • Lead / chemistry
  • Magnetic Resonance Spectroscopy

Substances

  • Environmental Pollutants
  • Cadmium
  • Lead