Abstract
Uroporphyrinogen oxidation by hepatic microsomes from chick embryos or mice pretreated with methylcholanthrene was increased by addition of iron-EDTA. This increase was partially prevented by catalase, mannitol, ketoconazole and piperonyl butoxide, whereas only ketoconazole and piperonyl butoxide inhibited the oxidation in the presence and absence of iron-EDTA. These data suggest that the oxidations of uroporphyrinogen in the presence and absence of added iron occur by different mechanisms.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Animals
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Catalase / metabolism
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Chick Embryo
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Edetic Acid / pharmacology*
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Ferric Compounds / pharmacology*
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Iron Chelating Agents / pharmacology*
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Ketoconazole / pharmacology
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Mice
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Microsomes, Liver / drug effects*
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Microsomes, Liver / enzymology
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Microsomes, Liver / metabolism
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Oxidation-Reduction
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Piperonyl Butoxide / pharmacology
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Polychlorinated Biphenyls / pharmacology
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Porphyrinogens / metabolism*
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Superoxide Dismutase / metabolism
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Uroporphyrinogens / metabolism*
Substances
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Ferric Compounds
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Iron Chelating Agents
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Porphyrinogens
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Uroporphyrinogens
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Edetic Acid
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Polychlorinated Biphenyls
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Catalase
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Superoxide Dismutase
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Fe(III)-EDTA
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Piperonyl Butoxide
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Ketoconazole
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3,4,3',4'-tetrachlorobiphenyl