Synthesis of key macrolactone structure of resin glycosides using a Keck macrolactonization method

J Asian Nat Prod Res. 2015;17(3):289-98. doi: 10.1080/10286020.2014.998653. Epub 2015 Jan 8.

Abstract

We present in this paper the efficient synthesis of three macrocyclic lactone units which are core structures of natural resin glycosides by the use of a Keck macrolactonization approach.

Keywords: Keck macrolactonization; macrolactone; resin glycoside; synthesis.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Glycosides / chemistry
  • Glycosides / isolation & purification*
  • Lactones / chemical synthesis*
  • Lactones / chemistry
  • Molecular Structure
  • Resins, Plant / chemistry*
  • Stereoisomerism

Substances

  • Glycosides
  • Lactones
  • Resins, Plant