Anion-induced Ag(I) self-assemblies with electron deficient aromatic ligands: anion-π-system interactions as a driving force for templated coordination networks

Chem Commun (Camb). 2015 Jun 11;51(46):9547-50. doi: 10.1039/c5cc01597a.

Abstract

Three novel 1D, 2D and 3D coordination polymers were successfully isolated using nitrogen based 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine (BPymTz) and 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) ligands with Ag(I) ions. The formation of these supramolecular assemblies was templated through anion-π-system interactions.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Anions / chemistry
  • Coordination Complexes / chemistry*
  • Electrons
  • Ligands
  • Polymers / chemistry
  • Pyrimidines / chemistry*
  • Silver / chemistry*
  • Triazines / chemistry*

Substances

  • Anions
  • Coordination Complexes
  • Ligands
  • Polymers
  • Pyrimidines
  • Triazines
  • Silver