Protective Polymer Coatings for High-Throughput, High-Purity Cellular Isolation

ACS Appl Mater Interfaces. 2015 Aug 19;7(32):17598-602. doi: 10.1021/acsami.5b06298. Epub 2015 Aug 7.

Abstract

Cell-based therapies are emerging as the next frontier of medicine, offering a plausible path forward in the treatment of many devastating diseases. Critically, current methods for antigen positive cell sorting lack a high throughput method for delivering ultrahigh purity populations, prohibiting the application of some cell-based therapies to widespread diseases. Here we show the first use of targeted, protective polymer coatings on cells for the high speed enrichment of cells. Individual, antigen-positive cells are coated with a biocompatible hydrogel which protects the cells from a surfactant solution, while uncoated cells are immediately lysed. After lysis, the polymer coating is removed through orthogonal photochemistry, and the isolate has >50% yield of viable cells and these cells proliferate at rates comparable to control cells. Minority cell populations are enriched from erythrocyte-depleted blood to >99% purity, whereas the entire batch process requires 1 h and <$2000 in equipment. Batch scale-up is only contingent on irradiation area for the coating photopolymerization, as surfactant-based lysis can be easily achieved on any scale.

Keywords: cell isolation; coatings; photopolymerization; polymer; protein expression; sorting.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Antibodies, Immobilized / immunology
  • Antigens, Neoplasm / immunology
  • Antigens, Neoplasm / metabolism
  • Biocompatible Materials / chemistry
  • Biocompatible Materials / pharmacology
  • Cell Adhesion Molecules / immunology
  • Cell Adhesion Molecules / metabolism
  • Cell Line, Tumor
  • Cell Proliferation / drug effects
  • Cell Separation / instrumentation
  • Cell Separation / methods*
  • Cell Survival / drug effects
  • Epithelial Cell Adhesion Molecule
  • Humans
  • Hydrogels / chemistry
  • Jurkat Cells
  • Leukocyte Common Antigens / immunology
  • Nanoparticles / chemistry
  • Polymers / chemistry*
  • Surface-Active Agents / chemistry

Substances

  • Antibodies, Immobilized
  • Antigens, Neoplasm
  • Biocompatible Materials
  • Cell Adhesion Molecules
  • Epithelial Cell Adhesion Molecule
  • Hydrogels
  • Polymers
  • Surface-Active Agents
  • Leukocyte Common Antigens