Comparative evaluation of two glycine transporter 1 radiotracers [11C]GSK931145 and [18F]MK-6577 in baboons

Synapse. 2016 Mar;70(3):112-20. doi: 10.1002/syn.21879. Epub 2016 Jan 6.

Abstract

Glycine transporter type-1 (GlyT1) has been proposed as a target for drug development for schizophrenia. PET imaging with a GlyT1 specific radiotracer will allow for the measurement of target occupancy of GlyT1 inhibitors, and for in vivo investigation of GlyT1 alterations in schizophrenia. We conducted a comparative evaluation of two GlyT1 radiotracers, [(11) C]GSK931145, and [(18) F]MK-6577, in baboons. Two baboons were imaged with [(11) C]GSK931145 and [(18) F]MK-6577. Blocking studies with GSK931145 (0.3 or 0.2 mg/kg) were conducted to determine the level of tracer specific binding. [(11) C]GSK931145 and [(18) F]MK-6577 were synthesized in good yield and high specific activity. Moderately fast metabolism was observed for both tracers, with ∼ 30% of parent at 30 min post-injection. In the brain, both radiotracers showed good uptake and distribution profiles consistent with regional GlyT1 densities. [(18) F]MK-6577 displayed higher uptake and faster kinetics than [(11) C]GSK931145. Time activity curves were well described by the two-tissue compartment model. Regional volume of distribution (VT ) values were higher for [(18) F]MK-6577 than [(11) C]GSK931145. Pretreatment with GSK931145 reduced tracer uptake to a homogeneous level throughout the brain, indicating in vivo binding specificity and lack of a reference region for both radiotracers. Linear regression analysis of VT estimates between tracers indicated higher specific binding for [(18) F]MK-6577 than [(11) C]GSK931145, consistent with higher regional binding potential (BPND ) values of [(18) F]MK-6577 calculated using VT from the baseline scans and non-displaceable distribution volume (VND ) derived from blocking studies. [(18) F]MK-6577 appears to be a superior radiotracer with higher brain uptake, faster kinetics, and higher specific binding signals than [(11) C]GSK931145.

Keywords: GlyT1; PET imaging; [11C]GSK931145; [18F]MK-6577.

Publication types

  • Comparative Study
  • Evaluation Study

MeSH terms

  • Animals
  • Benzamides* / chemical synthesis
  • Benzamides* / chemistry
  • Benzamides* / pharmacokinetics
  • Brain / diagnostic imaging
  • Brain / metabolism
  • Brain Mapping
  • Carbon Radioisotopes* / pharmacokinetics
  • Chromatography, High Pressure Liquid
  • Drug Evaluation, Preclinical
  • Female
  • Glycine Agents* / chemical synthesis
  • Glycine Agents* / chemistry
  • Glycine Agents* / pharmacokinetics
  • Glycine Plasma Membrane Transport Proteins / metabolism*
  • Kinetics
  • Linear Models
  • Magnetic Resonance Imaging
  • Molecular Structure
  • Papio
  • Positron-Emission Tomography
  • Radiopharmaceuticals* / chemical synthesis
  • Radiopharmaceuticals* / chemistry
  • Radiopharmaceuticals* / pharmacokinetics
  • Sulfonamides* / chemical synthesis
  • Sulfonamides* / chemistry
  • Sulfonamides* / pharmacokinetics

Substances

  • Benzamides
  • Carbon Radioisotopes
  • GSK 931145
  • Glycine Agents
  • Glycine Plasma Membrane Transport Proteins
  • MK-6577
  • Radiopharmaceuticals
  • Sulfonamides