A Simple Luminescent Adenylate-Cyclase Functional Assay for Evaluation of Bacillus anthracis Edema Factor Activity

Toxins (Basel). 2016 Aug 18;8(8):243. doi: 10.3390/toxins8080243.

Abstract

Edema Factor (EF), the toxic sub-unit of the Bacillus anthracis Edema Toxin (ET) is a calmodulin-dependent adenylate cyclase whose detrimental activity in the infected host results in severe edema. EF is therefore a major virulence factor of B. anthracis. We describe a simple, rapid and reliable functional adenylate-cyclase assay based on inhibition of a luciferase-mediated luminescence reaction. The assay exploits the efficient adenylate cyclase-mediated depletion of adenosine tri-phosphate (ATP), and the strict dependence on ATP of the light-emitting luciferase-catalyzed luciferin-conversion to oxyluciferin, which can be easily visualized. The assay exhibits a robust EF-dose response decrease in luminescence, which may be specifically reverted by anti-EF antibodies. The application of the assay is exemplified in: (a) determining the presence of EF in B. anthracis cultures, or its absence in cultures of EF-defective strains; (b) evaluating the anti-EF humoral response in experimental animals infected/vaccinated with B. anthracis; and (c) rapid discrimination between EF producing and non-producing bacterial colonies. Furthermore, the assay may be amenable with high-throughput screening for EF inhibitory molecules.

Keywords: ATP-depletion; Bacillus anthracis; Edema Factor; adenylate cyclase; luciferase; luminescent assay.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adenosine Triphosphate / metabolism
  • Adenylyl Cyclases / metabolism*
  • Antigens, Bacterial / metabolism*
  • Bacillus anthracis / enzymology*
  • Bacillus anthracis / genetics
  • Bacterial Toxins / metabolism*
  • High-Throughput Screening Assays / methods*
  • Indoles / metabolism
  • Kinetics
  • Luciferases / metabolism
  • Luminescent Measurements
  • Pyrazines / metabolism
  • Reproducibility of Results

Substances

  • Antigens, Bacterial
  • Bacterial Toxins
  • Indoles
  • Pyrazines
  • anthrax toxin
  • oxyluciferin
  • Adenosine Triphosphate
  • Luciferases
  • Adenylyl Cyclases