Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption

Yun-Wu Li; Hui Yan; Tong-Liang Hu; Hui-Yan Ma; Da-Cheng Li; Su-Na Wang; Qing-Xia Yao; Jian-Min Dou; Jian Xu; Xian-He Bu

doi:10.1039/c6cc09923h

Two microporous Fe-based MOFs with multiple active sites for selective gas adsorption

Chem Commun (Camb). 2017 Feb 16;53(15):2394-2397. doi: 10.1039/c6cc09923h.

Authors

Yun-Wu Li¹, Hui Yan², Tong-Liang Hu³, Hui-Yan Ma², Da-Cheng Li², Su-Na Wang², Qing-Xia Yao², Jian-Min Dou², Jian Xu³, Xian-He Bu³

Affiliations

¹ School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China. dougroup@163.com and School of Materials Science and Engineering, College of Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China. jxu@nankai.edu.cn buxh@nankai.edu.cn.
² School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China. dougroup@163.com.
³ School of Materials Science and Engineering, College of Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China. jxu@nankai.edu.cn buxh@nankai.edu.cn.

PMID: 28174776
DOI: 10.1039/c6cc09923h

Abstract

Two Fe-based porous MOFs have been constructed from dimeric Fe-clusters and rod-shaped heterobimetallic {Fe₂Na₃}_n chains as SBUs, respectively. Both of them exhibit highly selective CO₂ adsorption over CH₄ and N₂, owing to their abundant multiple active sites.