Discovery of a New Pterocarpan-Type Antineuroinflammatory Compound from Sophora tonkinensis through Suppression of the TLR4/NFκB/MAPK Signaling Pathway with PU.1 as a Potential Target

ACS Chem Neurosci. 2019 Jan 16;10(1):295-303. doi: 10.1021/acschemneuro.8b00243. Epub 2018 Sep 28.

Abstract

Neuroinflammation underlies many neuro-degenerative diseases. In this paper, we report the identification of a new pterocarpan-type anti-inflammatory compound named sophotokin isolated from Sophora tonkinensis. S. tonkinensis has been used traditionally for treatment of conditions related to inflammation. Our initial screening showed that sophotokin dose-dependently inhibits lipopolysaccharide (LPS)-stimulated production of NO, TNF-α, PGE2, and IL-1β in microglial cells. This antineuroinflammatory effect was associated with sophotokin's blockade of LPS-induced production of the inflammatory mediators iNOS and COX-2. Western blot and qPCR analysis demonstrated that sophotokin inhibits both the p38-MAPK and NF-κB signal pathways. Further studies revealed that sophotokin also suppresses the expression of cluster differentiation 14 (CD14) in the toll-like receptor 4 (TLR4) signaling pathway. Following down-regulation of MyD88 and TRAF6, sophotokin inhibits the activation of the NF-κB and MAPK signal pathways in LPS-induced BV-2 cells. In silico studies suggested that sophotokin could interact with PU.1-DNA complex through hydrogen binding at sites 1 and 2 of the complex, blocking the DNA binding. This suggests that PU.1 may be a potential target of sophotokin. Taken together, these results suggest that sophotokin may have therapeutic potential for diseases related to neuroinflammation. The mechanism of antineuroinflammatory effects involves inhibition of the TLR4 signal pathway at the sites of NF-κB and MAPK with PU.1 as a likely upstream target.

Keywords: Alzheimer’s diseases; BV-2; Sophora tonkinensis; microglia; neuroinflammation; pterocarpan.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Anti-Inflammatory Agents / chemistry
  • Anti-Inflammatory Agents / isolation & purification
  • Anti-Inflammatory Agents / pharmacology*
  • Cell Line
  • Cell Survival / drug effects
  • Cell Survival / physiology
  • Drug Discovery / methods
  • Inflammation Mediators / antagonists & inhibitors
  • Inflammation Mediators / metabolism
  • Mice
  • Mitogen-Activated Protein Kinases / antagonists & inhibitors*
  • Mitogen-Activated Protein Kinases / metabolism
  • Molecular Docking Simulation / methods
  • NF-kappa B / antagonists & inhibitors*
  • NF-kappa B / metabolism
  • Neuroprotective Agents / chemistry
  • Neuroprotective Agents / isolation & purification
  • Neuroprotective Agents / pharmacology
  • Plant Extracts / chemistry
  • Plant Extracts / isolation & purification
  • Plant Extracts / pharmacology
  • Proto-Oncogene Proteins / antagonists & inhibitors*
  • Proto-Oncogene Proteins / metabolism
  • Pterocarpans / chemistry
  • Pterocarpans / isolation & purification
  • Pterocarpans / pharmacology*
  • Signal Transduction / drug effects
  • Signal Transduction / physiology
  • Sophora*
  • Toll-Like Receptor 4 / antagonists & inhibitors*
  • Toll-Like Receptor 4 / metabolism
  • Trans-Activators / antagonists & inhibitors*
  • Trans-Activators / metabolism

Substances

  • Anti-Inflammatory Agents
  • Inflammation Mediators
  • NF-kappa B
  • Neuroprotective Agents
  • Plant Extracts
  • Proto-Oncogene Proteins
  • Pterocarpans
  • Tlr4 protein, mouse
  • Toll-Like Receptor 4
  • Trans-Activators
  • proto-oncogene protein Spi-1
  • Mitogen-Activated Protein Kinases