Inactivation and reactivation of the multifunctional calmodulin-dependent protein kinase from brain by autophosphorylation and dephosphorylation: involvement of protein phosphatases from brain

J Neurochem. 1987 Oct;49(4):1286-92. doi: 10.1111/j.1471-4159.1987.tb10022.x.

Abstract

The multifunctional calmodulin-dependent protein kinase (calmodulin-kinase) from rat brain was autophosphorylated in a Ca2+- and calmodulin-dependent manner. The activity of the autophosphorylated enzyme was independent of Ca2+ and calmodulin. Calmodulin-kinase was dephosphorylated by protein phosphatase C from bovine brain, which is the catalytic subunits of protein phosphatases 1 and 2A. The holoenzyme of protein phosphatase 2A was also involved in the dephosphorylation of the enzyme. The autophosphorylated sites of calmodulin-kinase were universally dephosphorylated by protein phosphatase C. Calmodulin-kinase was inactivated and reactivated by autophosphorylation and dephosphorylation, respectively. Furthermore, the regulation of calmodulin-kinase by autophosphorylation and dephosphorylation was observed using calmodulin-kinase from canine heart. These results suggest that the activity of calmodulin-kinase is regulated by autophosphorylation and dephosphorylation, and that the regulation is the universal phenomenon for many other calmodulin-kinases in various tissues.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Brain / enzymology*
  • Calcium / pharmacology
  • Calmodulin / pharmacology
  • Cations, Divalent
  • Cattle
  • Dogs
  • Enzyme Activation*
  • Enzyme Reactivators*
  • Kinetics
  • Myocardium / enzymology
  • Phosphoprotein Phosphatases / metabolism*
  • Phosphorylation
  • Protein Kinase Inhibitors
  • Protein Kinases / metabolism*
  • Protein Phosphatase 2
  • Rats
  • Sodium Fluoride / pharmacology

Substances

  • Calmodulin
  • Cations, Divalent
  • Enzyme Reactivators
  • Protein Kinase Inhibitors
  • Sodium Fluoride
  • Protein Kinases
  • Phosphoprotein Phosphatases
  • Protein Phosphatase 2
  • Calcium