Natural radioactivity and radiation hazard assessment of industrial wastes from the coastal phosphate treatment plants of Gabes (Tunisia, Southern Mediterranean Sea)

Abstract

This work is a first contribution to the knowledge of natural radionuclides (²²⁶Ra, ²³⁸U, ⁴⁰K, and ²³²Th) activities in phosphate rock (NORM), phosphogypsum, and phosphogypsum foam (TENORM) from the coastal fertilizer plants of Gabes (Southeastern Tunisia) and the assessment of their radiation hazards on human health and the surrounding environment. In the three studied materials, activities were found to be in the range of 35.4 (⁴⁰K)-375.1 (²²⁶Ra), 10.0 (⁴⁰K)-220.2 (²²⁶Ra), and 79.2 (²³²Th)-1168.6 Bq kg^-1 (²²⁶Ra), respectively. Considering the studied radionuclides and materials, the corresponding decreasing activity orders were found to be ²²⁶Ra > ²³⁸U > ⁴⁰K > ²³²Th and PGF > PR > PG, respectively. All human health hazard indices exceeded the worldwide recommended safety limits, which show that the workers in Gabes phosphate fertilizer plants as well as the neighboring human community may potentially be exposed to significant radiation, which may cause several diseases and malformations. It is therefore recommended to avoid and/or reduce the potential fertilizer industry radioactive impact in the area.

Keywords: Natural radioactivity; Phosphate rock; Phosphogypsum; Phosphogypsum foam; Radiation hazard assessment; Tunisian Chemical Group.