Evidence that the pyrromethane cofactor of hydroxymethylbilane synthase (porphobilinogen deaminase) is bound to the protein through the sulphur atom of cysteine-242

Biochem J. 1988 Sep 15;254(3):915-8. doi: 10.1042/bj2540915.

Abstract

The pyrromethane cofactor of hydroxymethylbilane synthase (porphobilinogen deaminase) from Escherichia coli is bound to the protein through the sulphur atom of a cysteine residue [Hart, Miller & Battersby (1988) Biochem. J. 252, 909-912; Beifuss, Hart, Miller & Battersby (1988) Tetrahedron Lett. 29, 2591-2594]. We show that the pyrromethane-binding residue is cysteine-242.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Ammonia-Lyases / metabolism*
  • Cysteine / analysis
  • Hydroxymethylbilane Synthase / metabolism*
  • Molecular Sequence Data
  • Peptide Fragments / analysis
  • Porphobilinogen / metabolism*
  • Protein Binding
  • Sulfur / analysis

Substances

  • Peptide Fragments
  • dipyrromethane cofactor
  • Sulfur
  • Porphobilinogen
  • Hydroxymethylbilane Synthase
  • Ammonia-Lyases
  • Cysteine