We report magnetoabsorption spectroscopy of gated WSe_{2} monolayers in high magnetic fields up to 60 T. When doped with a 2D Fermi sea of mobile holes, well-resolved sequences of optical transitions are observed in both σ^{±} circular polarizations, which unambiguously and separately indicate the number of filled Landau levels (LLs) in both K and K^{'} valleys. This reveals the interaction-enhanced valley Zeeman energy, which is found to be highly tunable with hole density p. We exploit this tunability to align the LLs in K and K^{'}, and find that the 2D hole gas becomes unstable against small changes in LL filling and can spontaneously valley polarize. These results cannot be understood within a single-particle picture, highlighting the importance of exchange interactions in determining the ground state of 2D carriers in monolayer semiconductors.