Amentadione from the Alga Cystoseira usneoides as a Novel Osteoarthritis Protective Agent in an Ex Vivo Co-Culture OA Model

Mar Drugs. 2020 Dec 7;18(12):624. doi: 10.3390/md18120624.

Abstract

Osteoarthritis (OA) remains a prevalent chronic disease without effective prevention and treatment. Amentadione (YP), a meroditerpenoid purified from the alga Cystoseira usneoides, has demonstrated anti-inflammatory activity. Here, we investigated the YP anti-osteoarthritic potential, by using a novel OA preclinical drug development pipeline designed to evaluate the anti-inflammatory and anti-mineralizing activities of potential OA-protective compounds. The workflow was based on in vitro primary cell cultures followed by human cartilage explants assays and a new OA co-culture model, combining cartilage explants with synoviocytes under interleukin-1β (IL-1β) or hydroxyapatite (HAP) stimulation. A combination of gene expression analysis and measurement of inflammatory mediators showed that the proposed model mimicked early disease stages, while YP counteracted inflammatory responses by downregulation of COX-2 and IL-6, improved cartilage homeostasis by downregulation of MMP3 and the chondrocytes hypertrophic differentiation factors Col10 and Runx2. Importantly, YP downregulated NF-κB gene expression and decreased phosphorylated IkBα/total IkBα ratio in chondrocytes. These results indicate the co-culture as a relevant pre-clinical OA model, and strongly suggest YP as a cartilage protective factor by inhibiting inflammatory, mineralizing, catabolic and differentiation processes during OA development, through inhibition of NF-κB signaling pathways, with high therapeutic potential.

Keywords: Cystoseira usneoides; amentadione; cartilage explants; chondrocytes; inflammation; marine compounds; mineralization; osteoarthritis; preclinical osteoarthritis models; synoviocytes.

MeSH terms

  • Anti-Inflammatory Agents, Non-Steroidal / pharmacology
  • Antirheumatic Agents / chemistry
  • Antirheumatic Agents / pharmacology*
  • Calcification, Physiologic / drug effects
  • Cartilage, Articular / drug effects
  • Cartilage, Articular / pathology
  • Chondrocytes / drug effects
  • Coculture Techniques
  • Cyanobacteria / chemistry*
  • Diterpenes / chemistry
  • Diterpenes / pharmacology*
  • Durapatite
  • Gene Expression / drug effects
  • Humans
  • Interleukin-1beta
  • Osteoarthritis / pathology
  • Osteoarthritis / prevention & control*
  • Primary Cell Culture
  • Synoviocytes / drug effects

Substances

  • Anti-Inflammatory Agents, Non-Steroidal
  • Antirheumatic Agents
  • Diterpenes
  • IL1B protein, human
  • Interleukin-1beta
  • amentadione
  • Durapatite