Expression, purification and characterisation of large quantities of recombinant human IAPP for mechanistic studies

Biophys Chem. 2021 Feb:269:106511. doi: 10.1016/j.bpc.2020.106511. Epub 2020 Nov 28.

Abstract

Malfunction and amyloid formation of the Islet Amyloid Polypeptide (IAPP) are factors contributing to Type 2 diabetes. Unravelling the mechanism of IAPP aggregate formation may forward our understanding of this process and its effect on pancreatic β-islet cell. Such mechanistic studies require access to sequence homogeneous and highly pure IAPP. Here we present a new facile protocol for the production of pure recombinant human IAPP at relatively high yield. The protocol uses a His-tagged version of the Npro mutant EDDIE, which drives expression to inclusion bodies, from which the peptide is purified using sonication, refolding and auto-cleavage, removal of EDDIE using Ni-NTA chromatography and reverse-phase HPLC. The purified material is used at multiple concentrations in aggregation kinetics measurements monitored by thioflavin-T fluorescence. Global analysis of the data implies a double nucleation aggregation mechanism including both primary and secondary nucleation.

MeSH terms

  • Chromatography, High Pressure Liquid
  • Escherichia coli / genetics
  • Escherichia coli / metabolism
  • Humans
  • Islet Amyloid Polypeptide* / chemistry
  • Islet Amyloid Polypeptide* / genetics
  • Islet Amyloid Polypeptide* / isolation & purification
  • Islet Amyloid Polypeptide* / metabolism
  • Kinetics
  • Protein Aggregates
  • Recombinant Proteins* / biosynthesis
  • Recombinant Proteins* / chemistry
  • Recombinant Proteins* / genetics
  • Recombinant Proteins* / isolation & purification
  • Recombinant Proteins* / metabolism

Substances

  • Islet Amyloid Polypeptide
  • Recombinant Proteins
  • Protein Aggregates