Synthesis and receptor dependent 4D-QSAR studies of 4,5-dihydro-1,3,4-oxadiazole derivatives targeting cannabinoid receptor

SAR QSAR Environ Res. 2021 Mar;32(3):175-190. doi: 10.1080/1062936X.2021.1879256. Epub 2021 Feb 23.

Abstract

Cannabinoid receptor has been shown to be overexpressed in various types of cancers, especially non-small cell lung cancer. As a result, it could be used as novel target for anticancer treatments. Because receptor-dependent 4D-QSAR generates conformational ensemble profiles of compounds by molecular dynamics simulations at the binding site of the enzyme, this work describes the synthesis, biological activity evaluation and 4D-QSAR studies of 4,5-dihydro-1,3,4-oxadiazole derivatives targeting cannabinoid receptor. Compared with WIN55,212-2, compound 5 f showed the best antiproliferative activity. The receptor-dependent 4D-QSAR model was generated by multiple linear regression method using QSARINS. Leave-n-out cross-validation and chemical applicability domain were performed to analyse the independent test set and to verify the robustness of the model. The best 4D-QSAR model showed the following statistics: r2 = 0.8487, Q2LOO = 0.7667, Q2LNO = 0.7524, and r2Pred = 0.8358.

Keywords: 3; 4; 4-oxadiazole; 4D-QSAR; 5-dihydro-1; Cannabinoid receptor; anticancer; synthesis.

MeSH terms

  • A549 Cells
  • Cell Proliferation / drug effects
  • Humans
  • Molecular Conformation
  • Molecular Dynamics Simulation
  • Oxadiazoles / chemical synthesis
  • Oxadiazoles / chemistry
  • Oxadiazoles / pharmacology*
  • Quantitative Structure-Activity Relationship*
  • Receptors, Cannabinoid / drug effects*

Substances

  • Oxadiazoles
  • Receptors, Cannabinoid
  • 1,3,4-oxadiazole