Influenza Virus Precision Diagnosis and Continuous Purification Enabled by Neuraminidase-Resistant Glycopolymer-Coated Microbeads

ACS Appl Mater Interfaces. 2021 Oct 6;13(39):46260-46269. doi: 10.1021/acsami.1c11561. Epub 2021 Sep 22.

Abstract

Rapid diagnosis and vaccine development are critical to prevent the threat posed by viruses. However, rapid tests, such as colloidal gold assays, yield false-negative results due to the low quantities of viruses; moreover, conventional virus purification, including ultracentrifugation and nanofiltration, is multistep and time-consuming, which limits laboratory research and commercial development of viral vaccines. A rapid virus enrichment and purification technique will improve clinical diagnosis sensitivity and simplify vaccine production. Hence, we developed the surface-glycosylated microbeads (glycobeads) featuring chemically synthetic glycoclusters and reversible linkers to selectively capture the influenza virus. The surface plasmon resonance (SPR) evaluation indicated broad spectrum affinity of S-linked glycosides to various influenza viruses. The magnetic glycobeads were integrated into clinical rapid diagnosis, leading to a 30-fold lower limit of detection. Additionally, the captured viruses can be released under physiological conditions, delivering purified viruses with >50% recovery and without decreasing their native infectivity. Notably, this glycobead platform will facilitate the sensitive detection and continuous one-step purification of the target virus that contributes to future vaccine production.

Keywords: S-linked sialosides; carbohydrate materials; influenza virus; virus purification; virus−carbohydrate interaction.

MeSH terms

  • Animals
  • Carbohydrate Sequence
  • Chromatography, Affinity
  • Dogs
  • HEK293 Cells
  • Humans
  • Influenza A Virus, H1N1 Subtype / chemistry
  • Influenza A Virus, H1N1 Subtype / isolation & purification*
  • Influenza, Human / diagnosis*
  • Limit of Detection
  • Madin Darby Canine Kidney Cells
  • Microspheres*
  • Polysaccharides / chemistry*
  • Surface Plasmon Resonance
  • Viral Load / methods*

Substances

  • Polysaccharides