Resolution of conformation equilibria in linear peptides by circular dichroism in cryogenic solvents

Biochem Biophys Res Commun. 1987 Mar 30;143(3):1005-11. doi: 10.1016/0006-291x(87)90351-2.

Abstract

The circular dichroism spectra of the synthetic peptide antigen, 209-222 of the surface glycoprotein of the rabies virus were recorded as a function of solvent composition and over the temperature range of +60 degrees C to -135 degrees C; beta-III and beta-II reverse turn conformations were found to exist in TFE/H2O (3:1) at room temperature and in ethanediol/H2O (2:1) below -110 degrees C respectively. Evidence, from comparison of observed and calculated spectra, is given to support the existence of a conformational equilibrium between a beta-II and a beta-III reverse turn. These data can serve as a basis for synthetic vaccine development and understanding the nature of polypeptide chain folding.

MeSH terms

  • Circular Dichroism
  • Glycoproteins / metabolism
  • Neurotoxins / metabolism
  • Peptide Fragments
  • Protein Conformation
  • Rabies Vaccines / isolation & purification
  • Rabies virus
  • Receptors, Cholinergic / metabolism
  • Solvents
  • Temperature
  • Viral Proteins* / metabolism

Substances

  • Glycoproteins
  • Neurotoxins
  • Peptide Fragments
  • Rabies Vaccines
  • Receptors, Cholinergic
  • Solvents
  • Viral Proteins