Bone lead variability in bone repository skeletal samples measured with portable x-ray fluorescence

Sci Total Environ. 2023 Jul 1:880:163197. doi: 10.1016/j.scitotenv.2023.163197. Epub 2023 Mar 29.

Abstract

Bone lead serves as a better, more accessible biomarker to many communities experiencing chronic exposure to lead. A new method using low energy x-ray fluorescence in a handheld device (portable XRF) allows us to measure this chronic biomarker in only a few minutes. However, many unknowns remain about this biomarker measured using a new low energy x-ray technique. The low energy of the new method was theorized to measure a slightly different portion of the bone than previous techniques, which could influence measurements at different bone sites and types. We tested how bone measurements varied across five bone sites: mid-tibial shaft, proximal tibia, distal tibia (ankle), ilium, and cranium. We found bone lead measurements are not significantly different between skeletal elements when measured using a portable XRF. On average, bone lead in the repository samples was measured to be 21.6 ± 21.3 μg/g with an XRF detection limit of 2.1 ± 0.5 μg/g. Cumulative lead exposure can be effectively measured using the portable XRF on a variety of bone types, but the tibia should be preferentially measured to compare between studies and individuals.

Keywords: Bone; Bone lead; Chronic; Lead; Tibia; XRF.

MeSH terms

  • Bone and Bones* / chemistry
  • Humans
  • Lead* / analysis
  • Radiography
  • Spectrometry, X-Ray Emission
  • X-Rays

Substances

  • Lead