Polydopamine-modification of a magnetic composite constructed from citric acid-cross-linked cyclodextrin and graphene oxide for dye removal from waters

Abstract

The effect of polydopamine (PDA) modification on aminated Fe₃O₄ nanoparticles (Fe₃O₄-NH₂)/graphite oxide (GO)/β-cyclodextrin polymer cross-linked by citric acid (CDP-CA) composites were studied for the removal of a cationic dye (methylene blue, MB) and an anionic dye (Congo red, CR) from waters. The micro-structural and magnetic characterizations confirmed the successful preparation of Fe₃O₄-NH₂/GO/CDP-CA and PDA/Fe₃O₄-NH₂/GO/CDP-CA composites. The maximum MB and CR adsorption capacities of Fe₃O₄-NH₂/GO/CDP-CA were 75 mg/g and 104 mg/g, respectively, while the corresponding amounts for PDA/Fe₃O4-NH₂/GO/CDP-CA composite were 195 mg/g and 64 mg/g, respectively. The dye sorption behaviors of these two composites were explained by their corresponding surface-charged properties according to the measured zeta potential results. Moreover, the high saturation magnetizations and the stable dye removal rate in the adsorption-desorption cycles indicated the good recyclability and reusability of the fabricated composites.

Keywords: Composite; Dye sorption; Fe3O4 nanoparticles; Graphite oxide; Polydopamine; β-Cyclodextrin polymer.