The AMP deaminase of the mollusk Helix pomatia is an unexpected member of the adenosine deaminase-related growth factor (ADGF) family

PLoS One. 2023 Jul 20;18(7):e0286435. doi: 10.1371/journal.pone.0286435. eCollection 2023.

Abstract

We report here the first occurrence of an adenosine deaminase-related growth factor (ADGF) that deaminates adenosine 5' monophosphate (AMP) in preference to adenosine. The ADGFs are a group of secreted deaminases found throughout the animal kingdom that affect the extracellular concentration of adenosine by converting it to inosine. The AMP deaminase studied here was first isolated and biochemically characterized from the roman snail Helix pomatia in 1983. Determination of the amino acid sequence of the AMP deaminase enabled sequence comparisons to protein databases and revealed it as a member of the ADGF family. Cloning and expression of its cDNA in Pichia pastoris allowed the comparison of the biochemical characteristics of the native and recombinant forms of the enzyme and confirmed they correspond to the previously reported activity. Uncharacteristically, the H. pomatia AMP deaminase was determined to be dissimilar to the AMP deaminase family by sequence comparison while demonstrating similarity to the ADGFs despite having AMP as its preferred substrate rather than adenosine.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • AMP Deaminase*
  • Adenosine / metabolism
  • Adenosine Deaminase / metabolism
  • Adenosine Monophosphate
  • Animals
  • Intercellular Signaling Peptides and Proteins
  • Mollusca / metabolism

Substances

  • AMP Deaminase
  • Adenosine Deaminase
  • Adenosine
  • Intercellular Signaling Peptides and Proteins
  • Adenosine Monophosphate

Grants and funding

This work was funded internally by New England Biolabs, Ipswich, MA, of which all authors are employees. The funder provided support in the form of salaries for: G.T., M.B.G., C.R., C.H.T., B.C., L. W., and I.S., but did not have any additional role in the study design, data collection and analysis, decision to publish, or preparation of the manuscript. The specific roles of these authors are articulated in the ‘author contributions’ section.