Contribution of aldehyde oxidase to methotrexate-induced hepatotoxicity: in vitro and pharmacoepidemiological approaches

Expert Opin Drug Metab Toxicol. 2024 May;20(5):399-406. doi: 10.1080/17425255.2024.2352453. Epub 2024 May 9.

Abstract

Background: Methotrexate (MTX) is partially metabolized by aldehyde oxidase (AOX) in the liver and its clinical impact remains unclear. In this study, we aimed to demonstrate how AOX contributes to MTX-induced hepatotoxicity in vitro and clarify the relationship between concomitant AOX inhibitor use and MTX-associated liver injury development using the U.S. Food and Drug Administration Adverse Event Reporting System (FAERS).

Methods: We assessed intracellular MTX accumulation and cytotoxicity using HepG2 cells. We used the FAERS database to detect reporting odds ratio (ROR)-based MTX-related hepatotoxicity event signals.

Results: AOX inhibition by AOX inhibitor raloxifene and siRNA increased the MTX accumulation in HepG2 cells and enhanced the MTX-induced cell viability reduction. In the FAERS analysis, the ROR for MTX-related hepatotoxicity increased with non-overlap of 95% confidence interval when co-administered with drugs with higher Imax, u (maximum unbound plasma concentration)/IC50 (half-maximal inhibitory concentration for inhibition of AOX) calculated based on reported pharmacokinetic data.

Conclusion: AOX inhibition contributed to MTX accumulation in the liver, resulting in increased hepatotoxicity. Our study raises concerns regarding MTX-related hepatotoxicity when co-administered with drugs that possibly inhibit AOX activity at clinical concentrations.

Keywords: Aldehyde oxidase; FAERS; drug-drug interaction; liver injury; methotrexate.

MeSH terms

  • Adverse Drug Reaction Reporting Systems*
  • Aldehyde Oxidase* / metabolism
  • Antimetabolites, Antineoplastic / administration & dosage
  • Antimetabolites, Antineoplastic / adverse effects
  • Cell Survival / drug effects
  • Chemical and Drug Induced Liver Injury* / etiology
  • Hep G2 Cells
  • Humans
  • Inhibitory Concentration 50
  • Methotrexate* / administration & dosage
  • Methotrexate* / adverse effects
  • RNA, Small Interfering / administration & dosage
  • RNA, Small Interfering / pharmacology
  • United States
  • United States Food and Drug Administration

Substances

  • Methotrexate
  • Aldehyde Oxidase
  • Antimetabolites, Antineoplastic
  • RNA, Small Interfering