Design and synthesis of matrine derivatives for anti myocardial ischemia-reperfusion injury by promoting angiogenesis

Bioorg Med Chem. 2024 Jun 15:108:117776. doi: 10.1016/j.bmc.2024.117776. Epub 2024 May 30.

Abstract

Myocardial ischemia/reperfusion (MI/R) is a common cardiovascular disease that seriously affects the quality of life and prognosis of patients. In recent years, matrine has attracted widespread attention in the treatment of cardiovascular diseases. This study designed, synthesized, and characterized 20 new matrine derivatives and studied their protective effects on ischemia-reperfusion injury through in vivo and in vitro experiments. Based on cellular assays, most newly synthesized derivatives have a certain protective effect on Hypoxia/Reoxygenation (H/R) induced H9C2 cell damage, with compound 22 having the best activity and effectively reducing cell apoptosis and necrosis. In vitro experimental data shows that compound 22 can significantly reduce the infarct size of rat myocardium and improve cardiac function after MI/R injury. In summary, compound 22 is a new potential cardioprotective agent that can promote angiogenesis and enhance antioxidant activity by activating ADCY5, CREB3l4, and VEGFA, thereby protecting myocardial cell apoptosis and necrosis induced by MI/R.

Keywords: ADCY5/CREB3l4/VEGFA; Angiogenic activator; Matrine derivatives; Myocardial ischemia–reperfusion injury.

MeSH terms

  • Alkaloids* / chemical synthesis
  • Alkaloids* / chemistry
  • Alkaloids* / pharmacology
  • Angiogenesis
  • Animals
  • Apoptosis* / drug effects
  • Cardiotonic Agents / chemical synthesis
  • Cardiotonic Agents / chemistry
  • Cardiotonic Agents / pharmacology
  • Cell Line
  • Dose-Response Relationship, Drug
  • Drug Design*
  • Male
  • Matrines*
  • Molecular Structure
  • Myocardial Reperfusion Injury* / drug therapy
  • Myocardial Reperfusion Injury* / pathology
  • Neovascularization, Physiologic / drug effects
  • Quinolizines* / chemical synthesis
  • Quinolizines* / chemistry
  • Quinolizines* / pharmacology
  • Rats
  • Rats, Sprague-Dawley*
  • Structure-Activity Relationship

Substances

  • Alkaloids
  • Matrines
  • Quinolizines
  • Cardiotonic Agents