The cytotoxic natural compound erianin binds to colchicine site of β-tubulin and overcomes taxane resistance

Bioorg Chem. 2024 Sep:150:107569. doi: 10.1016/j.bioorg.2024.107569. Epub 2024 Jun 17.

Abstract

Erianin, a natural compound derived from Dendrobium, has shown significant anticancer properties against a wide range of cancer cells. Despite the identification of multiple mechanisms of action for erianin, none of these mechanisms fully account for its broad-spectrum effect. In this study, we aimed to identify the cellular target and underlying mechanism responsible for the broad-spectrum antitumor effects of erianin. We found that erianin effectively inhibited tubulin polymerization in cancer cells and purified tubulin. Through competition binding assays and X-ray crystallography, it was revealed that erianin bound to the colchicine site of β-tubulin. Importantly, the X-ray crystal structure of the tubulin-erianin complex was solved, providing clear insight into the orientation and position of erianin in the colchicine-binding site. Erianin showed activity against paclitaxel-resistant cells, evidenced by G2/M cell cycle arrest, apoptosis-related PARP and Caspase-3 cleavage, and in vivo xenograft studies. The study concluded that erianin bound reversibly to the colchicine site of β-tubulin, inhibited tubulin polymerization, and displayed anticancer activity against paclitaxel-resistant cells, offering valuable insights for further exploration as potential anticancer agents.

Keywords: Colchicine site; Erianin; Microtubule; Paclitaxel resistant; Tubulin.

MeSH terms

  • Animals
  • Antineoplastic Agents* / chemical synthesis
  • Antineoplastic Agents* / chemistry
  • Antineoplastic Agents* / pharmacology
  • Apoptosis / drug effects
  • Bibenzyls / chemistry
  • Bibenzyls / pharmacology
  • Binding Sites
  • Biological Products / chemistry
  • Biological Products / pharmacology
  • Bridged-Ring Compounds / chemistry
  • Bridged-Ring Compounds / pharmacology
  • Cell Line, Tumor
  • Cell Proliferation* / drug effects
  • Colchicine* / chemistry
  • Colchicine* / metabolism
  • Colchicine* / pharmacology
  • Crystallography, X-Ray
  • Dose-Response Relationship, Drug
  • Drug Resistance, Neoplasm* / drug effects
  • Drug Screening Assays, Antitumor*
  • Humans
  • Mice
  • Mice, Nude
  • Molecular Structure
  • Phenol
  • Structure-Activity Relationship
  • Taxoids / chemistry
  • Taxoids / pharmacology
  • Tubulin Modulators / chemistry
  • Tubulin Modulators / pharmacology
  • Tubulin* / chemistry
  • Tubulin* / metabolism

Substances

  • Tubulin
  • Erianin
  • Colchicine
  • Antineoplastic Agents
  • Taxoids
  • Tubulin Modulators
  • Bridged-Ring Compounds
  • taxane
  • Biological Products
  • Bibenzyls
  • Phenol