Structural modeling and characterization of the Mycobacterium tuberculosis MmpL3 C-terminal domain

FEBS Lett. 2024 Nov;598(21):2734-2747. doi: 10.1002/1873-3468.15007. Epub 2024 Aug 28.

Abstract

The Mycobacterium tuberculosis (Mtb) cell envelope provides a protective barrier against the immune response and antibiotics. The mycobacterial membrane protein large (MmpL) family of proteins export cell envelope lipids and siderophores; therefore, these proteins are important for the basic biology and pathogenicity of Mtb. In particular, MmpL3 is essential and a known drug target. Despite interest in MmpL3, the structural data in the field are incomplete. Utilizing homology modeling, AlphaFold, and biophysical techniques, we characterized the cytoplasmic C-terminal domain (CTD) of MmpL3 to better understand its structure and function. Our in silico models of the MmpL11TB and MmpL3TB CTD reveal notable features including a long unstructured linker that connects the globular domain to the last transmembrane (TM) in each transporter, charged lysine and arginine residues facing the membrane, and a C-terminal alpha helix. Our predicted overall structure enables a better understanding of these transporters.

Keywords: Mycobacterium tuberculosis; MmpL11; MmpL3; molecular modeling; transporter.

MeSH terms

  • Amino Acid Sequence
  • Bacterial Proteins* / chemistry
  • Bacterial Proteins* / genetics
  • Bacterial Proteins* / metabolism
  • Membrane Transport Proteins / chemistry
  • Membrane Transport Proteins / genetics
  • Membrane Transport Proteins / metabolism
  • Models, Molecular*
  • Mycobacterium tuberculosis* / chemistry
  • Mycobacterium tuberculosis* / metabolism
  • Protein Domains*

Substances

  • Bacterial Proteins
  • MmpL3 protein, Mycobacterium tuberculosis
  • Membrane Transport Proteins