The development of efficient photocatalysts for sustainable hydrogen production via water splitting is vital for advancing renewable energy technologies. In this study, we present the synthesis and characterization of a novel visible-light-active photocatalyst comprising hedgehog-shaped zinc oxide (ZnO) nanostructures coupled with graphene quantum dots (GQDs). Optical properties assessed by UV-visible and photoluminescence (PL) spectroscopy revealed that the ZnO/GQDs heterostructure possessed a reduced band gap (2.86 eV) compared with pristine ZnO (3.10 eV), resulting in improved light absorption and charge separation. Electrochemical analyses indicated a significantly higher photocurrent response and lower charge transfer resistance for the ZnO/GQDs heterostructure compared with the pristine ZnO nanostructure. Photocatalytic tests demonstrated that the ZnO/GQDs heterostructure achieved over 3-fold higher hydrogen (H2) production rates, with an apparent quantum yield (AQY) of 1.51% at 440 nm, and maintained stable activity over prolonged reaction periods. These results highlight the enhanced photocatalytic efficiency and stability of the ZnO/GQDs heterostructure, underscoring its potential as a high-performance photocatalyst for sustainable hydrogen generation. The synergistic effects between ZnO nanostructures and GQDs offer valuable insights into the design of advanced photocatalytic materials for renewable energy applications.
© 2024 The Authors. Published by American Chemical Society.