Separation and enrichment of Cd and Pb from food and water samples based on a graphene oxide-decorated poly 2-diethylaminoethyl methacrylate nanocomposite by dispersive micro-solid phase extraction (d-μ-SPE)

Abstract

In this study, a graphene oxide combined with poly(2-diethylaminoethyl methacrylate) (GO@PDEAEMA) nanocomposite was synthesized for the separation and enrichment of Cd and Pb from food and water samples using the dispersive micro-solid phase extraction (d-μ-SPE) technique. The GO@PDEAEMA nanocomposite was synthesized using surface-initiated atom transfer radical polymerization (SI-ATRP) and characterized using various analytical techniques, such as FTIR, FE-SEM, TGA, BET, and XRD. The optimal experimental conditions were pH 8, 0.5 M HNO₃ as eluent, 5 mg of sorbent, and adsorption/desorption times of 0.5 and 1 min, respectively, with a recovery range of 89-101 %. The suggested method showed low limits of detection (LOD) and quantification (LOQ) of 0.11 μg L^-1 and 0.37 μg L^-1 for Cd and 0.28 μg L^-1 and 0.93 μg L^-1 for Pb, respectively. The optimal procedure was successfully applied to real water and food samples. The study demonstrates the possibility of using GO@PDEAEMA nanocomposite as an effective sorbent for toxic metal extraction.

Keywords: Cadmium; Dispersive micro-solid phase extraction (d-μ-SPE); GO@PDEAEMA; Lead; Water and food sample analysis.