Stretchable electronics have seen substantial development in skin-like mechanical properties and functionality thanks to the advancements made in intrinsically stretchable polymer electronic materials. Nanoscale phase separation of polymer materials within an elastic matrix to form one-dimensional nanostructures, namely nanoconfinement, effectively reduces conformational disorders that have long impeded charge transport properties of conjugated polymers. Nanoconfinement results in enhanced charge transport and the addition of skin-like properties. In this Outlook, we highlight the current understanding of structure-property relationships for intrinsically stretchable electronic materials with a focus on the nanoconfinement strategy as a promising approach to incorporate skin-like properties and other functionalities without compromising charge transport. We outline emerging directions and challenges for intrinsically stretchable electronic materials with the aim of constructing skin-like electronic systems.
© 2024 The Authors. Published by American Chemical Society.