The development of efficient hydrogen evolution reaction (HER) catalysts is crucial for water electrolysis. Currently, Ru-based catalysts are considered top contenders, but issues with stability, activity, and cost remain. In this work, RuNi alloys possessing a solid solution structure within the Ru lattice are prepared via straightforward electrodeposition on various substrates and assessed as HER catalysts in alkaline media. A RuNi solid solution containing 9.8 at. % Ni deposited on Ti substrate, wherein the Ni content greatly surpasses the solubility limit of Ni in Ru at room temperature, exhibits a considerably low overpotential of 28 mV at a current density of 10 mA cm- 2, along with good long-term stability (less than 100 mV increase in overpotential after 600 h). The enhancement in HER performance results from the increased electron density around Ru atoms due to Ni coordination, which facilitates the desorption of H* from the catalyst surface to produce H2. Concurrently, incorporating Ni reduces the Ru usage, rendering the RuNi alloy a viable cost-effective HER catalyst for practical applications.
Keywords: alkaline hydrogen evolution reaction; electrodeposition; electronic structure; ruthenium‐nickel alloy; solid solution.
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