The electrochemical activation and partial oxidation of methane are highly attractive to enable the direct conversion in a sustainable and decentralized way. Herein, we report an electrochemical system in a non-diaphragm electrochemical bath to convert CH4 to CH3OH and CH3CH2OH at room temperature, in which V3O7·H2O as the anodic catalyst to activate CH4 and an aprotic ionic liquid [BMIM]BF4 as supporting electrolyte to control superoxide radicals (O2-) as the main active oxygen species generated on cathode. As a result, methanol and ethanol were identified as the liquid products, and the superior methanol Faraday efficiency (FE) of 32.2 % and selectivity of 76.8 % can be reached. Molecular dynamics (MD) simulation indicates that interaction between CH4 molecules and [BMIM]BF4, which enhances the mass transfer in electrochemical reaction. Density function theory (DFT) calculation results suggest that the V sites in V3O7·H2O enhanced the chemisorption and dissociation of CH4 molecules on anode surface, then superoxide radicals (O2-) are supposed to be involved in the formation of methanol and ethanol.
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