Highly ordered two-dimensional crystals of photosystem I reaction center from Synechococcus sp.: functional and structural analyses

J Mol Biol. 1996 Sep 27;262(3):336-48. doi: 10.1006/jmbi.1996.0517.

Abstract

The photosystem 1 reaction center complex from the thermophilic cyanobacterium Synechococcus sp. was isolated by Triton X-100 solubilization and fractional precipitation with polyethylene glycol. As shown by gel electrophoresis, the isolated complex was composed of the 83 kDa subunits A and B, and at least six other subunits with molecular mass below 20 kDa. Electron transfer from the primary electron donor P700 to the FA/FB centers was demonstrated by flash-induced absorption change of the isolated complex, while electron paramagnetic resonance (EPR) spectroscopy showed that the complex contained a full set of Fe-S clusters. Isolated complexes were reconstituted into two-dimensional crystals in the presence of phospholipids and different cations. The crystals were found to be active by flash-induced separation and EPR spectroscopy. Electron microscopy and digital image processing of negatively stained and frozen-hydrated specimens revealed orthorhombic crystals with unit cell dimensions a = 138 A, b = 145 A and p12(1) symmetry. A three-dimensional map was calculated for negatively stained crystals to 19 A resolution, whereas the projection map of frozen-hydrated crystals exhibited 8 A resolution.

MeSH terms

  • Crystallization
  • Crystallography, X-Ray
  • Cyanobacteria / chemistry*
  • Electron Spin Resonance Spectroscopy
  • Freezing
  • Image Processing, Computer-Assisted
  • Lipid Bilayers
  • Lipid Metabolism
  • Lipids / chemistry
  • Microscopy, Electron / methods
  • Models, Chemical
  • Models, Molecular
  • Photosynthetic Reaction Center Complex Proteins / chemistry*
  • Photosynthetic Reaction Center Complex Proteins / metabolism
  • Photosynthetic Reaction Center Complex Proteins / ultrastructure*
  • Solubility

Substances

  • Lipid Bilayers
  • Lipids
  • Photosynthetic Reaction Center Complex Proteins