N-terminal truncation mutagenesis of equinatoxin II, a pore-forming protein from the sea anemone Actinia equina

Protein Eng. 1997 Jul;10(7):751-5. doi: 10.1093/protein/10.7.751.

Abstract

The role of the N-terminal segment 1-33 of equinatoxin II, a 20 kDa pore-forming protein from the sea anemone Actinia equina, was studied by N-truncation mutagenesis. A part of this segment was classified as being amphiphilic and membrane seeking. Wild-type equinatoxin II and its mutants lacking 5, 10 and 33 amino acid residues, respectively, were produced in Escherichia coli using T7 RNA polymerase-based expression vector. Soluble recombinant proteins were isolated from bacterial lysates and assayed for their inhibition by sphingomyelin, binding to red blood cells and hemolytic activity. The N-terminal deletion of 33 amino acids resulted in an insoluble protein, while mutants lacking 5 and 10 residues expressed increased relative avidity for sphingomyelin and red blood cell membranes. Their specific hemolytic activity was decreased, however, with increasing truncation. The results suggest that the N-terminus, which has been found to be conserved in sea anemone pore-forming toxins, contributes to the solubility of the equinatoxin II, but it is not essential for binding to lipid membranes. It is very likely that the N-terminus play a role in the formation of functional pores.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Base Sequence
  • Cattle
  • Cloning, Molecular
  • Cnidarian Venoms / genetics*
  • Cnidarian Venoms / metabolism
  • Cnidarian Venoms / toxicity
  • DNA Primers / genetics
  • Erythrocytes / metabolism
  • Escherichia coli / genetics
  • Hemolysis / drug effects
  • In Vitro Techniques
  • Molecular Sequence Data
  • Mutagenesis
  • Peptide Fragments / genetics
  • Peptide Fragments / metabolism
  • Peptide Fragments / toxicity
  • Polymerase Chain Reaction
  • Protein Engineering
  • Recombinant Proteins / genetics
  • Recombinant Proteins / metabolism
  • Recombinant Proteins / toxicity
  • Sea Anemones / genetics*
  • Sphingomyelins / pharmacology

Substances

  • Cnidarian Venoms
  • DNA Primers
  • Peptide Fragments
  • Recombinant Proteins
  • Sphingomyelins
  • equinatoxin