Toth K - Search Results

1

Product deuterium isotope effect for orotidine 5'-monophosphate decarboxylase: evidence for the existence of a short-lived carbanion intermediate.

Toth K, Amyes TL, Wood BM, Chan K, Gerlt JA, Richard JP. Toth K, et al. J Am Chem Soc. 2007 Oct 31;129(43):12946-7. doi: 10.1021/ja076222f. Epub 2007 Oct 5. J Am Chem Soc. 2007. PMID: 17918849 Free PMC article. No abstract available.

2

Formation and stability of N-heterocyclic carbenes in water: the carbon acid pKa of imidazolium cations in aqueous solution.

Amyes TL, Diver ST, Richard JP, Rivas FM, Toth K. Amyes TL, et al. Among authors: toth k. J Am Chem Soc. 2004 Apr 7;126(13):4366-74. doi: 10.1021/ja039890j. J Am Chem Soc. 2004. PMID: 15053626

3

Claisen-type addition of glycine to pyridoxal in water.

Toth K, Amyes TL, Richard JP, Malthouse JP, NíBeilliú ME. Toth K, et al. J Am Chem Soc. 2004 Sep 1;126(34):10538-9. doi: 10.1021/ja047501v. J Am Chem Soc. 2004. PMID: 15327301

4

Covalent catalysis by pyridoxal: evaluation of the effect of the cofactor on the carbon acidity of glycine.

Toth K, Richard JP. Toth K, et al. J Am Chem Soc. 2007 Mar 14;129(10):3013-21. doi: 10.1021/ja0679228. Epub 2007 Feb 14. J Am Chem Soc. 2007. PMID: 17298067 Free PMC article.

5

An examination of the relationship between active site loop size and thermodynamic activation parameters for orotidine 5'-monophosphate decarboxylase from mesophilic and thermophilic organisms.

Toth K, Amyes TL, Wood BM, Chan KK, Gerlt JA, Richard JP. Toth K, et al. Biochemistry. 2009 Aug 25;48(33):8006-13. doi: 10.1021/bi901064k. Biochemistry. 2009. PMID: 19618917 Free PMC article.

6

Product deuterium isotope effects for orotidine 5'-monophosphate decarboxylase: effect of changing substrate and enzyme structure on the partitioning of the vinyl carbanion reaction intermediate.

Toth K, Amyes TL, Wood BM, Chan K, Gerlt JA, Richard JP. Toth K, et al. J Am Chem Soc. 2010 May 26;132(20):7018-24. doi: 10.1021/ja102408k. J Am Chem Soc. 2010. PMID: 20441167 Free PMC article.

7

Isopentenyl diphosphate isomerase catalyzed reactions in D2O: product release limits the rate of this sluggish enzyme-catalyzed reaction.

Jonnalagadda V, Toth K, Richard JP. Jonnalagadda V, et al. Among authors: toth k. J Am Chem Soc. 2012 Apr 18;134(15):6568-70. doi: 10.1021/ja302154k. Epub 2012 Apr 5. J Am Chem Soc. 2012. PMID: 22471428 Free PMC article.

8

Claisen-type addition of glycine to a pyridoxal iminium ion in water.

Toth K, Gaskell LM, Richard JP. Toth K, et al. J Org Chem. 2006 Sep 1;71(18):7094-6. doi: 10.1021/jo061090e. J Org Chem. 2006. PMID: 16930073

9

The mandelamide keto-enol system in aqueous solution. Generation of the enol by hydration of phenylcarbamoylcarbene.

Chiang Y, Guo HX, Kresge AJ, Richard JP, Toth K. Chiang Y, et al. Among authors: toth k. J Am Chem Soc. 2003 Jan 8;125(1):187-94. doi: 10.1021/ja021017f. J Am Chem Soc. 2003. PMID: 12515521

10

Reactivity and selectivity of the N-acetyl-Glu-P-1, N-acetyl-Glu-P-2, N-acetyl-MeIQx, and N-acetyl-IQx nitrenium ions: comparison to carbocyclic N-arylnitrenium ions.

Novak M, Toth K, Rajagopal S, Brooks M, Hott LL, Moslener M. Novak M, et al. Among authors: toth k. J Am Chem Soc. 2002 Jul 10;124(27):7972-81. doi: 10.1021/ja0121944. J Am Chem Soc. 2002. PMID: 12095341

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