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ENDOR/HYSCORE studies of the common intermediate trapped during nitrogenase reduction of N2H2, CH3N2H, and N2H4 support an alternating reaction pathway for N2 reduction.
Lukoyanov D, Dikanov SA, Yang ZY, Barney BM, Samoilova RI, Narasimhulu KV, Dean DR, Seefeldt LC, Hoffman BM. Lukoyanov D, et al. Among authors: narasimhulu kv. J Am Chem Soc. 2011 Aug 3;133(30):11655-64. doi: 10.1021/ja2036018. Epub 2011 Jul 11. J Am Chem Soc. 2011. PMID: 21744838 Free PMC article.
Exploring by pulsed EPR the electronic structure of ubisemiquinone bound at the QH site of cytochrome bo3 from Escherichia coli with in vivo 13C-labeled methyl and methoxy substituents.
Lin MT, Shubin AA, Samoilova RI, Narasimhulu KV, Baldansuren A, Gennis RB, Dikanov SA. Lin MT, et al. Among authors: narasimhulu kv. J Biol Chem. 2011 Mar 25;286(12):10105-14. doi: 10.1074/jbc.M110.206821. Epub 2011 Jan 19. J Biol Chem. 2011. PMID: 21247900 Free PMC article.
Mycobacterium tuberculosis WhiB3 responds to O2 and nitric oxide via its [4Fe-4S] cluster and is essential for nutrient starvation survival.
Singh A, Guidry L, Narasimhulu KV, Mai D, Trombley J, Redding KE, Giles GI, Lancaster JR Jr, Steyn AJ. Singh A, et al. Among authors: narasimhulu kv. Proc Natl Acad Sci U S A. 2007 Jul 10;104(28):11562-7. doi: 10.1073/pnas.0700490104. Epub 2007 Jul 3. Proc Natl Acad Sci U S A. 2007. PMID: 17609386 Free PMC article.
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