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Structural characterization of CO-inhibited Mo-nitrogenase by combined application of nuclear resonance vibrational spectroscopy, extended X-ray absorption fine structure, and density functional theory: new insights into the effects of CO binding and the role of the interstitial atom.
Scott AD, Pelmenschikov V, Guo Y, Yan L, Wang H, George SJ, Dapper CH, Newton WE, Yoda Y, Tanaka Y, Cramer SP. Scott AD, et al. Among authors: cramer sp. J Am Chem Soc. 2014 Nov 12;136(45):15942-54. doi: 10.1021/ja505720m. Epub 2014 Nov 3. J Am Chem Soc. 2014. PMID: 25275608 Free PMC article.
Extended X-ray absorption fine structure and nuclear resonance vibrational spectroscopy reveal that NifB-co, a FeMo-co precursor, comprises a 6Fe core with an interstitial light atom.
George SJ, Igarashi RY, Xiao Y, Hernandez JA, Demuez M, Zhao D, Yoda Y, Ludden PW, Rubio LM, Cramer SP. George SJ, et al. Among authors: cramer sp. J Am Chem Soc. 2008 Apr 30;130(17):5673-80. doi: 10.1021/ja0755358. Epub 2008 Apr 2. J Am Chem Soc. 2008. PMID: 18386899 Free PMC article.
Direct Observation of an Iron-Bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy.
Reijerse EJ, Pham CC, Pelmenschikov V, Gilbert-Wilson R, Adamska-Venkatesh A, Siebel JF, Gee LB, Yoda Y, Tamasaku K, Lubitz W, Rauchfuss TB, Cramer SP. Reijerse EJ, et al. Among authors: cramer sp. J Am Chem Soc. 2017 Mar 29;139(12):4306-4309. doi: 10.1021/jacs.7b00686. Epub 2017 Mar 20. J Am Chem Soc. 2017. PMID: 28291336 Free PMC article.
Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by Nuclear Resonance Vibrational Spectroscopy and Density Functional Theory.
Pelmenschikov V, Birrell JA, Pham CC, Mishra N, Wang H, Sommer C, Reijerse E, Richers CP, Tamasaku K, Yoda Y, Rauchfuss TB, Lubitz W, Cramer SP. Pelmenschikov V, et al. Among authors: cramer sp. J Am Chem Soc. 2017 Nov 22;139(46):16894-16902. doi: 10.1021/jacs.7b09751. Epub 2017 Nov 9. J Am Chem Soc. 2017. PMID: 29054130 Free PMC article.
160 results