Five-coordinate complexes [FeX(depe)(2)]BPh(4), X = Cl, Br: electronic structure and spin-forbidden reaction with N(2).
Franke O, Wiesler BE, Lehnert N, Näther C, Ksenofontov V, Neuhausen J, Tuczek F.
Franke O, et al. Among authors: tuczek f.
Inorg Chem. 2002 Jul 1;41(13):3491-9. doi: 10.1021/ic0111987.
Inorg Chem. 2002.
PMID: 12079469
In contrast, the analogous dinitrogen complexes [FeX(N(2))(depe)(2)](+), X = Cl (2a) and Br (2b), characterized earlier are low-spin (S = 0; Wiesler, B. E.; Lehnert, N.; Tuczek, F.; Neuhausen, J.; Tremel, W. Angew. Chem, Int. Ed. 1998, 37, 815-817). N(2) bonding and …
In contrast, the analogous dinitrogen complexes [FeX(N(2))(depe)(2)](+), X = Cl (2a) and Br (2b), characterized earlier are low-spin (S = 0; …