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A Peroxodiiron(III/III) Intermediate Mediating Both N-Hydroxylation Steps in Biosynthesis of the N-Nitrosourea Pharmacophore of Streptozotocin by the Multi-domain Metalloenzyme SznF.
McBride MJ, Sil D, Ng TL, Crooke AM, Kenney GE, Tysoe CR, Zhang B, Balskus EP, Boal AK, Krebs C, Bollinger JM Jr. McBride MJ, et al. Among authors: crooke am. J Am Chem Soc. 2020 Jul 8;142(27):11818-11828. doi: 10.1021/jacs.0c03431. Epub 2020 Jun 24. J Am Chem Soc. 2020. PMID: 32511919 Free PMC article.