Xiong J - Search Results

1

10-Fold Increase in Hydrogen Atom Transfer Reactivity for a Series of S = 1 Fe^IV═O Complexes Over the S = 2 [(TQA)Fe^IV═O]²⁺ Complex via Entropic Lowering of Reaction Barriers by Secondary Sphere Cycloalkyl Substitution.

Das A, Pal N, Xiong J, Young VG Jr, Guo Y, Swart M, Que L Jr. Das A, et al. Among authors: xiong j. J Am Chem Soc. 2025 Jan 8;147(1):292-304. doi: 10.1021/jacs.4c10120. Epub 2024 Dec 19. J Am Chem Soc. 2025. PMID: 39699233

2

NMR and Mössbauer Studies Reveal a Temperature-Dependent Switch from S = 1 to 2 in a Nonheme Oxoiron(IV) Complex with Faster C-H Bond Cleavage Rates.

Rasheed W, Pal N, Aboelenen AM, Banerjee S, Oloo WN, Klein JEMN, Fan R, Xiong J, Guo Y, Que L Jr. Rasheed W, et al. Among authors: xiong j. J Am Chem Soc. 2024 Feb 14;146(6):3796-3804. doi: 10.1021/jacs.3c10694. Epub 2024 Feb 1. J Am Chem Soc. 2024. PMID: 38299607 Free PMC article.

3

Opening the Co^III,IV₂(μ-O)₂ Diamond Core by Lewis Bases Leads to Enhanced C-H Bond Cleaving Reactivity.

Li Y, Handunneththige S, Xiong J, Guo Y, Talipov MR, Wang D. Li Y, et al. Among authors: xiong j. J Am Chem Soc. 2020 Dec 30;142(52):21670-21678. doi: 10.1021/jacs.0c07294. Epub 2020 Dec 16. J Am Chem Soc. 2020. PMID: 33325694 Free PMC article.

4

A Mononuclear Non-heme Iron(III)-Peroxo Complex with an Unprecedented High O-O Stretch and Electrophilic Reactivity.

Zhu W, Jang S, Xiong J, Ezhov R, Li XX, Kim T, Seo MS, Lee YM, Pushkar Y, Sarangi R, Guo Y, Nam W. Zhu W, et al. Among authors: xiong j. J Am Chem Soc. 2021 Sep 29;143(38):15556-15561. doi: 10.1021/jacs.1c03358. Epub 2021 Sep 16. J Am Chem Soc. 2021. PMID: 34529428

5

Direct Activation of the C(sp³)-NH₂ Bond of Primary Aliphatic Alkylamines by a High-Valent Co^III,IV₂(μ-O)₂ Diamond Core Complex.

Li Y, Handunneththige S, Xiong J, Guo Y, Talipov MR, Wang D. Li Y, et al. Among authors: xiong j. J Am Chem Soc. 2023 Feb 1;145(4):2690-2697. doi: 10.1021/jacs.2c13199. Epub 2023 Jan 23. J Am Chem Soc. 2023. PMID: 36689463 Free PMC article.

6

Seeing the cis-Dihydroxylating Intermediate: A Mononuclear Nonheme Iron-Peroxo Complex in cis-Dihydroxylation Reactions Modeling Rieske Dioxygenases.

Zhu W, Kumar A, Xiong J, Abernathy MJ, Li XX, Seo MS, Lee YM, Sarangi R, Guo Y, Nam W. Zhu W, et al. Among authors: xiong j. J Am Chem Soc. 2023 Mar 1;145(8):4389-4393. doi: 10.1021/jacs.2c13551. Epub 2023 Feb 16. J Am Chem Soc. 2023. PMID: 36795537 Free PMC article.

7

Characterization of Methyl- and Acetyl-Ni Intermediates in Acetyl CoA Synthase Formed during Anaerobic CO₂ and CO Fixation.

Can M, Abernathy MJ, Wiley S, Griffith C, James CD, Xiong J, Guo Y, Hoffman BM, Ragsdale SW, Sarangi R. Can M, et al. Among authors: xiong j. J Am Chem Soc. 2023 Jun 28;145(25):13696-13708. doi: 10.1021/jacs.3c01772. Epub 2023 Jun 12. J Am Chem Soc. 2023. PMID: 37306669 Free PMC article.

8

Spin polarization assisted facile C-H activation by an S = 1 iron(iv)-bisimido complex: a comprehensive spectroscopic and theoretical investigation.

Xiong J, Liu Q, Lavina B, Hu MY, Zhao J, Alp EE, Deng L, Ye S, Guo Y. Xiong J, et al. Chem Sci. 2023 Feb 15;14(11):2808-2820. doi: 10.1039/d2sc06273a. eCollection 2023 Mar 15. Chem Sci. 2023. PMID: 36937578 Free PMC article.

9

Intramolecular C-H Oxidation in Iron(V)-oxo-carboxylato Species Relevant in the γ-Lactonization of Alkyl Carboxylic Acids.

Álvarez-Núñez A, Sarkar R, Dantignana V, Xiong J, Guo Y, Luis JM, Costas M, Company A. Álvarez-Núñez A, et al. Among authors: xiong j. ACS Catal. 2024 Sep 11;14(18):14183-14194. doi: 10.1021/acscatal.4c01258. eCollection 2024 Sep 20. ACS Catal. 2024. PMID: 39324053 Free PMC article.

10

⁵⁷Fe nuclear resonance vibrational spectroscopic studies of tetranuclear iron clusters bearing terminal iron(iii)-oxido/hydroxido moieties.

Xiong J, Reed C, Lavina B, Hu MY, Zhao J, Alp EE, Agapie T, Guo Y. Xiong J, et al. Chem Sci. 2024 Sep 9;15(39):16222-33. doi: 10.1039/d4sc03396e. Online ahead of print. Chem Sci. 2024. PMID: 39296996 Free PMC article.

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