Saponin Molecules from Quinoa Residues: Exploring Their Surfactant, Emulsifying, and Detergent Properties

Molecules. 2024 Oct 18;29(20):4928. doi: 10.3390/molecules29204928.

Abstract

The indiscriminate use of synthetic surfactants, despite their desirable properties, poses significant environmental risks to ecosystems. This study explores saponins extracted from quinoa (Chenopodium quinoa) residues as a sustainable alternative. Saponin extract (SE) with 42% purity, obtained through hydrodynamic cavitation and membrane technology, was analyzed to determine its techno-functional properties. The critical micelle concentration (CMC) was 1.2 g/L, reducing the surface tension (ST) from 72.0 mN/m to 50.0 mN/m. The effects of temperature (30-90 °C), pH (2-12), and salinity (10,000-150,000 ppm NaCl) on ST and the emulsification index (EI) were assessed using a Box-Behnken design. Optimized conditions yielded an ST of 49.02 mN/m and an EI of 63%. Given these characteristics, SE was evaluated as a detergent across diverse swatches. This study showcases the attributes of quinoa-derived saponins, highlighting their potential for eco-friendly detergent applications.

Keywords: Chenopodium quinoa; circular economy; saponin; surfactant properties.

MeSH terms

  • Chenopodium quinoa* / chemistry
  • Detergents* / chemistry
  • Emulsions / chemistry
  • Hydrogen-Ion Concentration
  • Micelles
  • Plant Extracts / chemistry
  • Saponins* / chemistry
  • Surface Tension*
  • Surface-Active Agents* / chemistry
  • Temperature

Substances

  • Saponins
  • Surface-Active Agents
  • Detergents
  • Plant Extracts
  • Micelles
  • Emulsions