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265 results

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Page 1
Carbonyl and ester C-O bond hydrosilylation using kappa(4)-diimine nickel catalysts.
Rock CL , Groy TL , Trovitch RJ . Rock CL , et al. Dalton Trans. 2018 Jul 3;47(26):8807-8816. doi: 10.1039/c8dt01857j. Dalton Trans. 2018. PMID: 29922802
However, when an equimolar solution of allyl acetate and phenyl silane was added to 1.0 mol% (Ph2PPrDI)Ni, complete ester C-O bond hydrosilylation was observed within 30 min at 25 C to generate propylene and PhSi(OAc)3. ...This activity is believed to be the highest …
However, when an equimolar solution of allyl acetate and phenyl silane was added to 1.0 mol% (Ph2PPrDI)Ni, complete ester C-O …
Determination of plasma and leukocyte vitamin C concentrations in a randomized, double-blind, placebo-controlled trial with Ester-C().
Mitmesser SH, Ye Q, Evans M, Combs M. Mitmesser SH, et al. Springerplus. 2016 Jul 25;5(1):1161. doi: 10.1186/s40064-016-2605-7. eCollection 2016. Springerplus. 2016. PMID: 27512620 Free PMC article.
The objective of this study was to evaluate the bioavailability of vitamin C in plasma (reflective of recent intake) and leukocytes (reflective of tissue stores and influences on immune function) from a novel vitamin C formulation, Ester-C(). METHODS: The study was …
The objective of this study was to evaluate the bioavailability of vitamin C in plasma (reflective of recent intake) and leukocytes (reflect …
Safety and tolerance of ester-C compared with regular ascorbic acid.
Gruenwald J, Graubaum HJ, Busch R, Bentley C. Gruenwald J, et al. Adv Ther. 2006 Jan-Feb;23(1):171-8. doi: 10.1007/BF02850358. Adv Ther. 2006. PMID: 16644619 Clinical Trial.
The goal of this randomized, double-blind crossover clinical trial in 50 healthy volunteers sensitive to acidic foods was to evaluate whether Ester-C calcium ascorbate causes fewer epigastric adverse effects than are produced by regular ascorbic acid ( …
The goal of this randomized, double-blind crossover clinical trial in 50 healthy volunteers sensitive to acidic foods was to evaluate whethe …
Iron-Catalyzed C(sp2)-C(sp3) Cross-Coupling of Aryl Chlorobenzoates with Alkyl Grignard Reagents.
Bisz E, Szostak M. Bisz E, et al. Molecules. 2020 Jan 6;25(1):230. doi: 10.3390/molecules25010230. Molecules. 2020. PMID: 31935934 Free PMC article.
It is notable that high selectivity for the cross-coupling is achieved in the presence of hydrolytically-labile and prone to nucleophilic addition phenolic ester C(acyl)-O bonds. The reaction provides access to alkyl-functionalized aryl benzoates. The examination of …
It is notable that high selectivity for the cross-coupling is achieved in the presence of hydrolytically-labile and prone to nucleophilic ad …
Thermodynamic Strategies for C-O Bond Formation and Cleavage via Tandem Catalysis.
Lohr TL, Li Z, Marks TJ. Lohr TL, et al. Acc Chem Res. 2016 May 17;49(5):824-34. doi: 10.1021/acs.accounts.6b00069. Epub 2016 Apr 14. Acc Chem Res. 2016. PMID: 27078085
This Account reviews recent developments on thermodynamically leveraged tandem catalysis for ether and more recently, ester C-O bond cleavage undertaken at Northwestern University. First, the fundamentals of lanthanide-catalyzed hydroelementation are reviewed, with …
This Account reviews recent developments on thermodynamically leveraged tandem catalysis for ether and more recently, ester C- …
Advanced oxidation processes for phthalate esters removal in aqueous solution: a systematic review.
Amiri H, Martinez SS, Shiri MA, Soori MM. Amiri H, et al. Rev Environ Health. 2022 Feb 14;38(2):197-218. doi: 10.1515/reveh-2021-0147. Print 2023 Jun 27. Rev Environ Health. 2022. PMID: 37261847 Review.
In different AOP processes, the aromatic rings of PE are destroyed by ()OH and produce intermediates such as phthalic acid (C(6)H(4)(CO(2)H)(2)), benzoic acid ethyl ester (C(9)H(10)O(2)), 2, 5-dihydroxybenzoic acid (C(7)H(6)O(4)), formic acid (CH(2)O(2)), acetic aci …
In different AOP processes, the aromatic rings of PE are destroyed by ()OH and produce intermediates such as phthalic acid (C(6)H(4)(CO(2)H) …
Triflate's bigger brother: The unprecedented tribrate anion, [Br3 CSO3 ].
Mertens A, Eppers K, van Gerven D, Wickleder MS. Mertens A, et al. Chemistry. 2024 Feb 21;30(11):e202303617. doi: 10.1002/chem.202303617. Epub 2024 Jan 24. Chemistry. 2024. PMID: 38264922
The formation of the [CBr(3) ] moiety has been proved, also by an X-ray structure determination of the compound (triclinic, P-1, a=685.9(2), b=698.1(2), c=1190.2(3) pm, alpha=93.99(1), beta=97.42(1), gamma=94.45(1)). The ester C(6) H(5) OSO(2) CBr(3) can be split un …
The formation of the [CBr(3) ] moiety has been proved, also by an X-ray structure determination of the compound (triclinic, P-1, a=685.9(2), …
2,4,6-Tri-nitro-phenyl 3-bromo-benzoate.
Moreno-Fuquen R, Mosquera F, Ellena J, Tenorio JC. Moreno-Fuquen R, et al. Acta Crystallogr Sect E Struct Rep Online. 2014 May 21;70(Pt 6):o689. doi: 10.1107/S1600536814010952. eCollection 2014 Jun 1. Acta Crystallogr Sect E Struct Rep Online. 2014. PMID: 24940266 Free PMC article.
In the title picryl-substituted ester, C13H6BrN3O8, the mean plane of the central ester C-O-C(=O)-C fragment (r.m.s. deviation= 0.0186 A) is rotated by 84.73 (7) and 19.92 (12) to the picryl and phenyl rings, respectively. ...
In the title picryl-substituted ester, C13H6BrN3O8, the mean plane of the central ester C-O-C(=O)-C fragment (r.m.s. deviation …
Cyclodecyl 4-nitrophenylacetate.
Brown J, Pawar DM, Fronczek FR, Noe EA. Brown J, et al. Acta Crystallogr C. 2006 Oct;62(Pt 10):o628-30. doi: 10.1107/S0108270106035049. Epub 2006 Sep 21. Acta Crystallogr C. 2006. PMID: 17008754
An intermolecular contact exists between the ester C atom and a nitro O atom, having a C...O distance of 2.909 (2) A....
An intermolecular contact exists between the ester C atom and a nitro O atom, having a C...O distance of 2.909 (2) A....
265 results